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Extraneous carbon assessments in radiocarbon measurements of black carbon in environmental matrices


Coppola, Alysha I; Ziolkowski, Lori A; Druffel, Ellen R M (2013). Extraneous carbon assessments in radiocarbon measurements of black carbon in environmental matrices. Radiocarbon, 55(2-3):1631-1640.

Abstract

Extraneous carbon (Cex) added during chemical processing and isolation of black carbon (BC) in environmental matrices was quantified to assess its impact on compound specific radiocarbon analysis (CSRA). Extraneous carbon is added during the multiple steps of BC extraction, such as incomplete removal of solvents, and carbon bleed from the gas chromatographic and cation columns. We use 2 methods to evaluate the size and Δ14C values of Cex in BC in ocean sediments that require additional pretreatment using a cation column with the benzene polycarboxylic acid (BPCA) method. First, the direct method evaluates the size and Δ14C value of Cex directly from the process blank, generated by processing initially empty vials through the entire method identically to the treatment of a sample. Second, the indirect method quantifies Cex as the difference between processed and unprocessed (bulk) Δ14C values in a variety of modern and 14C-free or “dead” BC standards. Considering a suite of hypothetical marine sedimentary samples of various sizes and Δ14C values and BC Ring Trial standards, we compare both methods of corrections and find agreement between samples that are >50 µg C. Because Cex can profoundly influence the measured Δ14C value of compound specific samples, we strongly advocate the use of multiple types of process standards that match the sample size to assess Cex and investigate corrections throughout extensive sample processing.

Abstract

Extraneous carbon (Cex) added during chemical processing and isolation of black carbon (BC) in environmental matrices was quantified to assess its impact on compound specific radiocarbon analysis (CSRA). Extraneous carbon is added during the multiple steps of BC extraction, such as incomplete removal of solvents, and carbon bleed from the gas chromatographic and cation columns. We use 2 methods to evaluate the size and Δ14C values of Cex in BC in ocean sediments that require additional pretreatment using a cation column with the benzene polycarboxylic acid (BPCA) method. First, the direct method evaluates the size and Δ14C value of Cex directly from the process blank, generated by processing initially empty vials through the entire method identically to the treatment of a sample. Second, the indirect method quantifies Cex as the difference between processed and unprocessed (bulk) Δ14C values in a variety of modern and 14C-free or “dead” BC standards. Considering a suite of hypothetical marine sedimentary samples of various sizes and Δ14C values and BC Ring Trial standards, we compare both methods of corrections and find agreement between samples that are >50 µg C. Because Cex can profoundly influence the measured Δ14C value of compound specific samples, we strongly advocate the use of multiple types of process standards that match the sample size to assess Cex and investigate corrections throughout extensive sample processing.

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4 citations in Web of Science®
4 citations in Scopus®
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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Institute of Geography
Dewey Decimal Classification:910 Geography & travel
Language:English
Date:2013
Deposited On:29 Mar 2016 16:09
Last Modified:31 May 2016 07:48
Publisher:Department of Geosciences, University of Arizona
ISSN:0033-8222
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.2458/azu_js_rc.55.16303

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