UZH-Logo

Maintenance Infos

[mu]-1,2-Bis(diethylphosphino)ethane-[kappa]2P:P'-bis{[1,2-bis(diethylphosphino)ethane-[kappa]2P,P']trichloridonitrosyltungsten(II)}


Avramovic, N; Blacque, O; Schmalle, H W; Berke, H (2008). [mu]-1,2-Bis(diethylphosphino)ethane-[kappa]2P:P'-bis{[1,2-bis(diethylphosphino)ethane-[kappa]2P,P']trichloridonitrosyltungsten(II)}. Acta Crystallographica. Section E, Structure Reports Online, 64(2):M367-M368.

Abstract

The title binuclear compound, [W2Cl6(NO)2(C10H22P2)3], contains two W atoms which are bridged by a bis(diethylphosphino)ethane (depe) ligand. The seven-coordinated tungsten(II) centres display distorted pentagonal-bipyramidal geometries with trans nitrosyl and chloride ligands. The title molecule lies on a crystallographic inversion centre. The ethane group of the non-bridging depe ligand is positionally disordered, with site-occupancy factors of 0.63 and 0.37. In the crystal structure, the binuclear molecules are linked by weak intermolecular C-H...O and C-H...Cl interactions. In addition, weak intramolecular C-H...Cl interactions are also present.

Abstract

The title binuclear compound, [W2Cl6(NO)2(C10H22P2)3], contains two W atoms which are bridged by a bis(diethylphosphino)ethane (depe) ligand. The seven-coordinated tungsten(II) centres display distorted pentagonal-bipyramidal geometries with trans nitrosyl and chloride ligands. The title molecule lies on a crystallographic inversion centre. The ethane group of the non-bridging depe ligand is positionally disordered, with site-occupancy factors of 0.63 and 0.37. In the crystal structure, the binuclear molecules are linked by weak intermolecular C-H...O and C-H...Cl interactions. In addition, weak intramolecular C-H...Cl interactions are also present.

Altmetrics

Downloads

37 downloads since deposited on 15 Feb 2009
14 downloads since 12 months
Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:February 2008
Deposited On:15 Feb 2009 12:20
Last Modified:05 Apr 2016 12:59
Publisher:Wiley-Blackwell
ISSN:1600-5368
Publisher DOI:https://doi.org/10.1107/S1600536808001141

Download

[img]
Preview
Filetype: PDF
Size: 1MB
View at publisher

TrendTerms

TrendTerms displays relevant terms of the abstract of this publication and related documents on a map. The terms and their relations were extracted from ZORA using word statistics. Their timelines are taken from ZORA as well. The bubble size of a term is proportional to the number of documents where the term occurs. Red, orange, yellow and green colors are used for terms that occur in the current document; red indicates high interlinkedness of a term with other terms, orange, yellow and green decreasing interlinkedness. Blue is used for terms that have a relation with the terms in this document, but occur in other documents.
You can navigate and zoom the map. Mouse-hovering a term displays its timeline, clicking it yields the associated documents.

Author Collaborations