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The cyano carbonyl complexes [(99)Tc(CN)(3)(CO)(3)]2- and [Re(CN)(3)(CO)(3)]2- were synthesized and fully characterized. These complexes are additional members of the well-known d(6) transition metal complex series [M(CN)(3)(CO)(3)](n-). The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.
|Item Type:||Journal Article, refereed|
|Communities & Collections:||07 Faculty of Science > Institute of Inorganic Chemistry|
|Date:||28 June 2004|
|Deposited On:||11 Feb 2008 13:25|
|Last Modified:||23 Nov 2012 14:30|
|Publisher:||American Chemical Society|
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