Kurz, P; Spingler, B; Fox, T; Alberto, R (2004). [TcI(CN)3(CO)3]2- and [ReI(CN)3(CO)3]2- :case studies for the binding properties of CN- and CO. Inorganic Chemistry, 43(13):3789-3791.
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The cyano carbonyl complexes [(99)Tc(CN)(3)(CO)(3)]2- and [Re(CN)(3)(CO)(3)]2- were synthesized and fully characterized. These complexes are additional members of the well-known d(6) transition metal complex series [M(CN)(3)(CO)(3)](n-). The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.
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|Item Type:||Journal Article, refereed|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Date:||28 June 2004|
|Deposited On:||11 Feb 2008 12:25|
|Last Modified:||27 Nov 2013 21:27|
|Publisher:||American Chemical Society|
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