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[TcI(CN)3(CO)3]2- and [ReI(CN)3(CO)3]2- :case studies for the binding properties of CN- and CO.


Kurz, P; Spingler, B; Fox, T; Alberto, R (2004). [TcI(CN)3(CO)3]2- and [ReI(CN)3(CO)3]2- :case studies for the binding properties of CN- and CO. Inorganic Chemistry, 43(13):3789-3791.

Abstract

The cyano carbonyl complexes [(99)Tc(CN)(3)(CO)(3)]2- and [Re(CN)(3)(CO)(3)]2- were synthesized and fully characterized. These complexes are additional members of the well-known d(6) transition metal complex series [M(CN)(3)(CO)(3)](n-). The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.

The cyano carbonyl complexes [(99)Tc(CN)(3)(CO)(3)]2- and [Re(CN)(3)(CO)(3)]2- were synthesized and fully characterized. These complexes are additional members of the well-known d(6) transition metal complex series [M(CN)(3)(CO)(3)](n-). The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.

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11 citations in Web of Science®
12 citations in Scopus®
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Additional indexing

Item Type:Journal Article, refereed
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:28 June 2004
Deposited On:11 Feb 2008 12:25
Last Modified:05 Apr 2016 12:20
Publisher:American Chemical Society
ISSN:0020-1669
Publisher DOI:10.1021/ic049774x
PubMed ID:15206855

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