Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-17454
Ernst, K H (2008). Expression and amplification of chirality in two-dimensional molecular crystals. CHIMIA International Journal for Chemistry, 62(6):471-475.
View at publisher
Chirality can be bestowed onto achiral surfaces by adsorption of chiral molecules. This offers a good opportunity to study two-dimensional chiral crystallization phenomena, like lateral resolution of enantiomers or the transfer of handedness from single molecules into mesoscopic ensembles with high resolution by scanning probe microscopy. Induction of homochirality on surfaces via cooperatively amplified interactions in molecular monolayers is a new phenomenon of supramolecular surface chirality. Prochiral molecules will turn into either handedness upon adsorption, but doping with intrinsically chiral molecules breaks this symmetry and induces homochirality. A similar effect is induced by a small enantiomeric excess. The excess molecules provide the chiral bias that becomes amplified into single lattice chirality.
118 downloads since deposited on 05 Mar 2009
13 downloads since 12 months
|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Dewey Decimal Classification:||540 Chemistry|
|Deposited On:||05 Mar 2009 19:09|
|Last Modified:||05 Jun 2014 13:09|
|Publisher:||Swiss Chemical Society|
|Additional Information:||Copyright ©Swiss Chemical Society: CHIMIA,62:471-475,2008|
Users (please log in): suggest update or correction for this item
Repository Staff Only: item control page