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A facile and novel route to unprecedented manganese C4 cumulenic complexes.


Venkatesan, K; Fernández, F J; Blacque, Olivier; Fox, T; Alfonso, M; Schmalle, H W; Berke, Heinz (2003). A facile and novel route to unprecedented manganese C4 cumulenic complexes. Chemical Communications, 16:2006-2008.

Abstract

The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) [=C=C=C=C(SnPh3)2] was obtained by photolysis of the C(sp2)-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)-C[triple bond]CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn-C4-SnPh3.

The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) [=C=C=C=C(SnPh3)2] was obtained by photolysis of the C(sp2)-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)-C[triple bond]CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn-C4-SnPh3.

Citations

24 citations in Web of Science®
8 citations in Scopus®
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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:21 August 2003
Deposited On:11 Feb 2008 12:25
Last Modified:05 Apr 2016 12:20
Publisher:Royal Society of Chemistry
ISSN:1359-7345
Publisher DOI:10.1039/b304882a
PubMed ID:12934885

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