UZH-Logo

Electronic Communication in C(4)-Bridged Binuclear Complexes with Paramagnetic Bisphosphane Manganese End Groups.


Kheradmandan, S; Heinze, K; Schmalle, H W; Berke, Heinz (1999). Electronic Communication in C(4)-Bridged Binuclear Complexes with Paramagnetic Bisphosphane Manganese End Groups. Angewandte Chemie International Edition, 38(15):2270-2273.

Abstract

Building blocks for conducting polymers or NLO materials are the linear, unsaturated carbon chain bridged manganese complexes 1(n+) (n=0-2). All oxidation states were investigated spectroscopically and by X-ray structure determinations. The analytical data confirm a communication of the electrons over the C(4) chain-a prerequisite for electrical conductivity and NLO properties of oligo- or polymeric materials.

Building blocks for conducting polymers or NLO materials are the linear, unsaturated carbon chain bridged manganese complexes 1(n+) (n=0-2). All oxidation states were investigated spectroscopically and by X-ray structure determinations. The analytical data confirm a communication of the electrons over the C(4) chain-a prerequisite for electrical conductivity and NLO properties of oligo- or polymeric materials.

Citations

Altmetrics

Additional indexing

Item Type:Journal Article, refereed
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Uncontrolled Keywords:Alkynyl complexes, Electron transfer, Manganese, Metal-metal interactions, Mixed-valent compounds
Language:English
Date:1 August 1999
Deposited On:11 Feb 2008 12:25
Last Modified:05 Apr 2016 12:20
Publisher:Wiley-Blackwell
ISSN:1433-7851
Publisher DOI:10.1002/(SICI)1521-3773(19990802)38:15<2270::AID-ANIE2270>3.0.CO;2-6
Related URLs:http://www3.interscience.wiley.com/cgi-bin/abstract/63000280/ABSTRACT
PubMed ID:10425507

Download

Full text not available from this repository.View at publisher

TrendTerms

TrendTerms displays relevant terms of the abstract of this publication and related documents on a map. The terms and their relations were extracted from ZORA using word statistics. Their timelines are taken from ZORA as well. The bubble size of a term is proportional to the number of documents where the term occurs. Red, orange, yellow and green colors are used for terms that occur in the current document; red indicates high interlinkedness of a term with other terms, orange, yellow and green decreasing interlinkedness. Blue is used for terms that have a relation with the terms in this document, but occur in other documents.
You can navigate and zoom the map. Mouse-hovering a term displays its timeline, clicking it yields the associated documents.

Author Collaborations