Kheradmandan, S; Heinze, K; Schmalle, H W; Berke, Heinz (1999). Electronic Communication in C(4)-Bridged Binuclear Complexes with Paramagnetic Bisphosphane Manganese End Groups. Angewandte Chemie International Edition, 38(15):2270-2273.
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Abstract
Building blocks for conducting polymers or NLO materials are the linear, unsaturated carbon chain bridged manganese complexes 1(n+) (n=0-2). All oxidation states were investigated spectroscopically and by X-ray structure determinations. The analytical data confirm a communication of the electrons over the C(4) chain-a prerequisite for electrical conductivity and NLO properties of oligo- or polymeric materials.
| Item Type: | Journal Article, refereed |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Institute of Inorganic Chemistry |
| DDC: | 540 Chemistry |
| Uncontrolled Keywords: | Alkynyl complexes, Electron transfer, Manganese, Metal-metal interactions, Mixed-valent compounds |
| Language: | English |
| Date: | 01 August 1999 |
| Deposited On: | 11 Feb 2008 13:25 |
| Last Modified: | 23 Nov 2012 15:00 |
| Publisher: | Wiley-Blackwell |
| ISSN: | 1433-7851 |
| Publisher DOI: | 10.1002/(SICI)1521-3773(19990802)38:15<2270::AID-ANIE2270>3.0.CO;2-6 |
| Related URLs: | http://www3.interscience.wiley.com/cgi-bin/abstract/63000280/ABSTRACT |
| PubMed ID: | 10425507 |
| WoS Citation Count: | 107 |
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