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Kheradmandan, S; Heinze, K; Schmalle, H W; Berke, Heinz (1999). Electronic Communication in C(4)-Bridged Binuclear Complexes with Paramagnetic Bisphosphane Manganese End Groups. Angewandte Chemie International Edition, 38(15):2270-2273.

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Abstract

Building blocks for conducting polymers or NLO materials are the linear, unsaturated carbon chain bridged manganese complexes 1(n+) (n=0-2). All oxidation states were investigated spectroscopically and by X-ray structure determinations. The analytical data confirm a communication of the electrons over the C(4) chain-a prerequisite for electrical conductivity and NLO properties of oligo- or polymeric materials.

Item Type:Journal Article, refereed
Communities & Collections:07 Faculty of Science > Department of Chemistry
DDC:540 Chemistry
Uncontrolled Keywords:Alkynyl complexes, Electron transfer, Manganese, Metal-metal interactions, Mixed-valent compounds
Language:English
Date:1 August 1999
Deposited On:11 Feb 2008 12:25
Last Modified:28 Nov 2013 00:20
Publisher:Wiley-Blackwell
ISSN:1433-7851
Publisher DOI:10.1002/(SICI)1521-3773(19990802)38:15<2270::AID-ANIE2270>3.0.CO;2-6
Related URLs:http://www3.interscience.wiley.com/cgi-bin/abstract/63000280/ABSTRACT
PubMed ID:10425507
Citations:Web of Science®. Times Cited: 115
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