Quick Search:

uzh logo
Browse by:
bullet
bullet
bullet
bullet

Zurich Open Repository and Archive

Maintenance: Tuesday, 5.7.2016, 07:00-08:00

Maintenance work on ZORA and JDB on Tuesday, 5th July, 07h00-08h00. During this time there will be a brief unavailability for about 1 hour. Please be patient.

Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-31170

Bürgi, J J; Mariz, R; Gatti, M; Drinkel, E; Luan, X; Blumentritt, S; Linden, A; Dorta, R (2009). Unprecedented selectivity via electronic substrate recognition in the 1,4-addition to cyclic olefins using a chiral disulfoxide Rhodium catalyst. Angewandte Chemie International Edition, 48(15):2768-2771.

[img] PDF - Registered users only
1MB
View at publisher

Abstract

From zero to hero? Sulfoxides are generally not considered useful ligand entities in asymmetric metal catalysis. However, a chiral disulfoxide as a chelating ligand in the rhodium-catalyzed 1,4-addition of aryl boronic acids to cyclic, ,-unsaturated ketones and esters gives impressive catalytic results, thus opening the door to future applications of this new chiral ligand class.

Citations

59 citations in Web of Science®
62 citations in Scopus®
Google Scholar™

Altmetrics

Downloads

1 download since deposited on 18 Feb 2010
0 downloads since 12 months

Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2009
Deposited On:18 Feb 2010 18:16
Last Modified:05 Apr 2016 13:57
Publisher:Wiley-Blackwell
ISSN:1433-7851
Funders:Alfred Werner Foundation, SNF, Roche Research Foundation
Publisher DOI:10.1002/anie.200900429

Users (please log in): suggest update or correction for this item

Repository Staff Only: item control page