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Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-31170

Bürgi, J J; Mariz, R; Gatti, M; Drinkel, E; Luan, X; Blumentritt, S; Linden, A; Dorta, R (2009). Unprecedented selectivity via electronic substrate recognition in the 1,4-addition to cyclic olefins using a chiral disulfoxide Rhodium catalyst. Angewandte Chemie International Edition, 48(15):2768-2771.

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Abstract

From zero to hero? Sulfoxides are generally not considered useful ligand entities in asymmetric metal catalysis. However, a chiral disulfoxide as a chelating ligand in the rhodium-catalyzed 1,4-addition of aryl boronic acids to cyclic, ,-unsaturated ketones and esters gives impressive catalytic results, thus opening the door to future applications of this new chiral ligand class.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
DDC:540 Chemistry
Language:English
Date:2009
Deposited On:18 Feb 2010 18:16
Last Modified:05 Jun 2014 13:08
Publisher:Wiley-Blackwell
ISSN:1433-7851
Funders:Alfred Werner Foundation, SNF, Roche Research Foundation
Publisher DOI:10.1002/anie.200900429
Citations:Web of Science®. Times Cited: 44
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Scopus®. Citation Count: 47

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