Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-33800
Atanassov, P K; Linden, A; Heimgartner, H (2010). Reactions of 4-(Diethylamino)selenet-2(2H)-imine with Nucleophiles - Synthesis of 2-Methylen-3-oxobutane Selenoamides. Letters in Organic Chemistry, 7(4):291-297.
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3-Acetyl-N-(4-bromophenyl)-4-(diethylamino)selenet-2(2H)-imine (5a), which is conveniently obtained from the formal [2+2] cycloaddition of 4-bromophenyl isoselenocyanate and 4-(diethylamino)-3-butyn-2-one, reacts with amines, alcohols, water, and thiophenol to give the corresponding 2-methylen-3-oxobutane selenoamides 7 in good yields via ring opening to the ketenimine 6 and subsequent addition of the nucleophile.
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|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Deposited On:||18 May 2010 10:50|
|Last Modified:||05 Jun 2014 13:06|
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