Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-33800
Atanassov, P K; Linden, A; Heimgartner, H (2010). Reactions of 4-(Diethylamino)selenet-2(2H)-imine with Nucleophiles - Synthesis of 2-Methylen-3-oxobutane Selenoamides. Letters in Organic Chemistry, 7(4):291-297.
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Abstract
3-Acetyl-N-(4-bromophenyl)-4-(diethylamino)selenet-2(2H)-imine (5a), which is conveniently obtained from the formal [2+2] cycloaddition of 4-bromophenyl isoselenocyanate and 4-(diethylamino)-3-butyn-2-one, reacts with amines, alcohols, water, and thiophenol to give the corresponding 2-methylen-3-oxobutane selenoamides 7 in good yields via ring opening to the ketenimine 6 and subsequent addition of the nucleophile.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Institute of Organic Chemistry |
| DDC: | 540 Chemistry |
| Language: | English |
| Date: | April 2010 |
| Deposited On: | 18 May 2010 12:50 |
| Last Modified: | 23 Nov 2012 17:12 |
| Publisher: | Bentham Science |
| ISSN: | 1570-1786 |
| Publisher DOI: | 10.2174/157017810791130685 |
| Official URL: | http://www.bentham.org/loc/contabs/loc7-4.htm#4 |
| WoS Citation Count: | 0 |
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