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Conformations of an amino–amido–thiolate self-assembled layer on gold in air and in electrolytes


Bittner, A M; Epple, M; Kuhnke, K; Houriet, R; Heusler, A; Vogel, H; Seitsonen, A P; Kern, K (2003). Conformations of an amino–amido–thiolate self-assembled layer on gold in air and in electrolytes. Journal of Electroanalytical Chemistry, 550-55:113-124.

Abstract

The amino-amido-thiol AT (HS-(CHZ)(10)-CO-NH-CHz-CHZ-NH2), adsorbed on Au(111), was studied by sum frequency generation (SFG) and infrared reflection absorption spectroscopy in the CHZ stretching vibration region. The SFG and infrared spectra are qualitatively similar; both show the symmetric stretching band and an intense and unusually broad antisymmetric stretching band. The infrared spectra show a reversible difference between a sample dried after rinsing in electrolyte and dried after rinsing in ethanol, thus exhibiting a `solvent memory' effect. SFG spectra demonstrate that the dried samples have a high density of conformational defects. The defects are located in the C-10 methylene chain. We ascribe them to intermolecular hydrogen-bonding. When the layer is studied by SFG spectroscopy in aqueous solution, even in the presence of coordinating Pd2+ ions no vibrational bands are observed in the CHZ stretching vibration region. This indicates a strongly reduced defect density with a straightened molecular backbone. We ascribe this to the solvation of the amine group; in this case intermolecular bonds play a minor role.

The amino-amido-thiol AT (HS-(CHZ)(10)-CO-NH-CHz-CHZ-NH2), adsorbed on Au(111), was studied by sum frequency generation (SFG) and infrared reflection absorption spectroscopy in the CHZ stretching vibration region. The SFG and infrared spectra are qualitatively similar; both show the symmetric stretching band and an intense and unusually broad antisymmetric stretching band. The infrared spectra show a reversible difference between a sample dried after rinsing in electrolyte and dried after rinsing in ethanol, thus exhibiting a `solvent memory' effect. SFG spectra demonstrate that the dried samples have a high density of conformational defects. The defects are located in the C-10 methylene chain. We ascribe them to intermolecular hydrogen-bonding. When the layer is studied by SFG spectroscopy in aqueous solution, even in the presence of coordinating Pd2+ ions no vibrational bands are observed in the CHZ stretching vibration region. This indicates a strongly reduced defect density with a straightened molecular backbone. We ascribe this to the solvation of the amine group; in this case intermolecular bonds play a minor role.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2003
Deposited On:27 Mar 2009 08:03
Last Modified:05 Apr 2016 12:27
Publisher:Elsevier
ISSN:0022-0728
Publisher DOI:10.1016/S0022-0728(03)00136-0
Permanent URL: http://doi.org/10.5167/uzh-3436

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