Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-3439
Clair, S; Pons, S; Seitsonen, A P; Brune, H; Kern, K; Barth, J V (2004). STM study of terephthalic acid self-assembly on Au(111): Hydrogen-bonded sheets on an inhomogeneous substrate. Journal of Physical Chemistry. B, 108(38):14585-14590.
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The adsorption and ordering of the molecule terephthalic acid (TPA), 1,4-benzene-dicarboxylic acid C6H4-(COOH)(2), on the reconstructed Au(111) surface has been studied in situ in ultrahigh vacuum by scanning tunneling microscopy (STM) at room temperature. Two-dimensional (2D) self-assembled supramolecular domains evolve, wherein the well-known one-dimensional (1D) carboxyl H-bond pairing scheme is identified. Since the individual molecules occupy a distinct adsorption site and the supramolecular ordering usually extends over several substrate reconstruction domains, a significant variation in hydrogen bond lengths is encountered, which illustrates the versatility of hydrogen bridges in molecular engineering at surfaces. Ab initio calculations for a 1D H-bonded molecular chain provide insight into the limited geometric response of the molecules in different local environments.
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|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Dewey Decimal Classification:||540 Chemistry|
|Deposited On:||26 Mar 2009 20:53|
|Last Modified:||05 Jun 2014 13:51|
|Publisher:||American Chemical Society|
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