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Molybdenum(VI) Amino Triphenolate Complexes as Catalysts for Sulfoxidation, Epoxidation and Haloperoxidation


Romano, F; Linden, A; Mba, M; Zonta, C; Licini, G (2010). Molybdenum(VI) Amino Triphenolate Complexes as Catalysts for Sulfoxidation, Epoxidation and Haloperoxidation. Advanced Synthesis & Catalysis, 352:2937-2942.

Abstract

Two molybdenum(VI) complexes bearing a C3 symmetrical amino tris-tert-butylphenolate ligand have proved to be air- and water-tolerant catalysts that efficiently catalyse, in high yields and selectivity, the oxidation of sulfides, olefins and halides. In particular high turnover frequencies and turnover numbers (TOF and TON) have been obtained for the cyclooctene epoxidation (catalyst loading down to 0.05%, TONs up to 88,000 and TOFs up to 7500 h−1)

Two molybdenum(VI) complexes bearing a C3 symmetrical amino tris-tert-butylphenolate ligand have proved to be air- and water-tolerant catalysts that efficiently catalyse, in high yields and selectivity, the oxidation of sulfides, olefins and halides. In particular high turnover frequencies and turnover numbers (TOF and TON) have been obtained for the cyclooctene epoxidation (catalyst loading down to 0.05%, TONs up to 88,000 and TOFs up to 7500 h−1)

Citations

29 citations in Web of Science®
29 citations in Scopus®
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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2010
Deposited On:24 Jan 2011 15:12
Last Modified:05 Apr 2016 14:26
Publisher:Wiley-Blackwell
ISSN:1615-4150
Funders:Fondazione Cassa di Risparmio di Padova e Rovigo, Assegni di ricerca 2006, PRIN 2008 (MIUR), PRAT 2009, COST, Action D40
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.1002/adsc.201000496

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