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t-3-Benzyl-r-2c-6-bis(4-methoxyphenyl)piperidin-4-one oxime


Jaybharathi, J; Thangamani, A; Balamurugan, S; Thiruvalluvar, A; Linden, A (2008). t-3-Benzyl-r-2c-6-bis(4-methoxyphenyl)piperidin-4-one oxime. Acta Crystallographica. Section E, Structure Reports Online, 64(7):o1211.

Abstract

In the title molecule, C26H28N2O3, the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15) deg. The benzyl group at position 3 has an equatorial orientation. The oxime group at position 4 has a bisectional orientation. The ring of the benzyl group makes dihedral angles of 64.71 (16) and 84.79 (17) deg. with the two benzene rings. Molecules are linked by intermolecular N-H...O, O-H...N and C-H...O hydrogen bonds, and C—H...pi interactions. There is also a C-H...O intramolecular interaction.

In the title molecule, C26H28N2O3, the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15) deg. The benzyl group at position 3 has an equatorial orientation. The oxime group at position 4 has a bisectional orientation. The ring of the benzyl group makes dihedral angles of 64.71 (16) and 84.79 (17) deg. with the two benzene rings. Molecules are linked by intermolecular N-H...O, O-H...N and C-H...O hydrogen bonds, and C—H...pi interactions. There is also a C-H...O intramolecular interaction.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:6 June 2008
Deposited On:17 Oct 2008 10:48
Last Modified:05 Apr 2016 12:30
Publisher:Wiley-Blackwell
ISSN:1600-5368
Funders:UGC, India, Minor Research Project [File No. MRP-2355/06 (UGC-SERO), Link No. 2355, 10/01/2007]
Publisher DOI:10.1107/S1600536808016449
Permanent URL: http://doi.org/10.5167/uzh-4354

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