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Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-44990

Kunz, P C; Wetzel, C; Bongartz, M; Noffke, A L; Spingler, B (2010). Novel multitopic diphos-type ligands. Journal of Organometallic Chemistry, 695(15-16):1891-1897.

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Abstract

Seven novel imidazole and thiazole derivatives of diphos-type ligands are presented. They are of the general structure R2P(CH2)(2)PR2, where R is imidazol-2-yl (1), 1-methylimidazol-2-yl (2), 1-methyl-benzimidazol-2-yl (3), 1-methylimidazol-5-yl (4), 2-isopropylimidazol-4(5)-yl (5), thiazol-2-yl (6), benzothiazol-2-yl (7), thiazol-4-yl (8) or thiazol-5-yl (9). Syntheses involved direct metallation or halogen-metal exchange reactions. Their solubility, especially in aqueous solution, is strongly dependent on the nature of the substituents as is their partition coefficient log D. The crystal structures of compounds 2, 3, 7a and 9 as well as the structure of the rhodium complex (2)(2)Rh2Cl2]Cl-2 (10) have been determined. (C) 2010 Elsevier B. V. All rights reserved.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Institute of Inorganic Chemistry
DDC:540 Chemistry
Uncontrolled Keywords:Phosphane ligands; Nitrogen heterocycles; Imidazoles; Thiazoles
Language:English
Date:2010
Deposited On:08 Feb 2011 15:04
Last Modified:09 Dec 2013 19:48
Publisher:Elsevier
ISSN:0022-328X
Publisher DOI:10.1016/j.jorganchem.2010.04.028
Other Identification Number:ISI:000279590700010
Citations:Web of Science®. Times Cited: 6
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