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High-yield synthesis and crystal structure determination of sodium triphenylphosphane monosulfonate (TPPMSNa)


Karschin, A; Klaeui, W; Peters, W; Spingler, B (2010). High-yield synthesis and crystal structure determination of sodium triphenylphosphane monosulfonate (TPPMSNa). European Journal of Inorganic Chemistry, (6):942-946.

Abstract

A simple, high-yield synthesis is described that leads to the sodium salt of monosulfonated triphenylphosphane (TPPMSNa) as a pure product in large quantities without complicated workup techniques, The single-crystal X-ray structure of TPPMSNa center dot 2.5H(2)O is reported. The structure is built up by alternating layers of aquated sodium sulfonate units and hydrophobic triphenyl units. Thermogravimetric analyses show the loss of one molecule of water at 70 and one at 105 degrees C. Thermal decomposition occurs at temperatures above 400 degrees C. The anhydrous ligand is hygroscopic. The preparation of the free acid TPPMSH starting from the sodium salt is also reported. TPPMSH is an extremely hygroscopic solid that could not be isolated in the crystalline form.

A simple, high-yield synthesis is described that leads to the sodium salt of monosulfonated triphenylphosphane (TPPMSNa) as a pure product in large quantities without complicated workup techniques, The single-crystal X-ray structure of TPPMSNa center dot 2.5H(2)O is reported. The structure is built up by alternating layers of aquated sodium sulfonate units and hydrophobic triphenyl units. Thermogravimetric analyses show the loss of one molecule of water at 70 and one at 105 degrees C. Thermal decomposition occurs at temperatures above 400 degrees C. The anhydrous ligand is hygroscopic. The preparation of the free acid TPPMSH starting from the sodium salt is also reported. TPPMSH is an extremely hygroscopic solid that could not be isolated in the crystalline form.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Uncontrolled Keywords:Phosphane ligands; Surfactants; Sulfur; Structure elucidation
Language:English
Date:2010
Deposited On:08 Feb 2011 13:42
Last Modified:05 Apr 2016 14:44
Publisher:Wiley-Blackwell
ISSN:1434-1948
Publisher DOI:10.1002/ejic.200901002
Other Identification Number:ISI:000275240500014

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