Pitchumony, T S; Spingler, B; Motterlini, R; Alberto, R (2010). Syntheses, structural characterization and CO releasing properties of boranocarbonate H3BCO2H](-) derivatives. Organic & Biomolecular Chemistry, 8(21):4849-4854.
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CO plays an important role in biological processes and molecules which release CO in a controllable way could therefore be used for medicinal purposes. Beside organometallic carbonyl complexes, boranocarbonate H3BCO2H](-) is one of the most promising candidates but releases CO too rapidly. In order to delay the CO release, we have prepared boranocarbamates H3BCONH-R] from H3BCO2H] which comprise histamine, morpholine, aniline and ethylene-diamine bound via amides to the moiety. The syntheses of the new derivatives is described together with their structural characterization. These compounds release CO at a much slower rate than the parent compound and are therefore potential CO releasing molecules for biological and medicinal application.
|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Deposited On:||25 Feb 2011 13:48|
|Last Modified:||27 Nov 2013 22:05|
|Publisher:||Royal Society of Chemistry|
|Other Identification Number:||ISI:000282872600013|
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