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Pitchumony, T S; Spingler, B; Motterlini, R; Alberto, R (2010). Syntheses, structural characterization and CO releasing properties of boranocarbonate H3BCO2H](-) derivatives. Organic & Biomolecular Chemistry, 8(21):4849-4854.

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Abstract

CO plays an important role in biological processes and molecules which release CO in a controllable way could therefore be used for medicinal purposes. Beside organometallic carbonyl complexes, boranocarbonate H3BCO2H](-) is one of the most promising candidates but releases CO too rapidly. In order to delay the CO release, we have prepared boranocarbamates H3BCONH-R] from H3BCO2H] which comprise histamine, morpholine, aniline and ethylene-diamine bound via amides to the {H3BCO} moiety. The syntheses of the new derivatives is described together with their structural characterization. These compounds release CO at a much slower rate than the parent compound and are therefore potential CO releasing molecules for biological and medicinal application.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
DDC:540 Chemistry
Language:English
Date:2010
Deposited On:25 Feb 2011 13:48
Last Modified:27 Nov 2013 22:05
Publisher:Royal Society of Chemistry
ISSN:1477-0520
Publisher DOI:10.1039/c0ob00099j
PubMed ID:20734000
Other Identification Number:ISI:000282872600013
Citations:Web of Science®. Times Cited: 25
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Scopus®. Citation Count: 25

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