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Braband, H; Imstepf, S; Felber, M; Spingler, B; Alberto, R (2010). Triazacyclohexane (tach) complexes of high-valent rhenium: syntheses of [(R(3)tach)ReO(3)](+) (R = -CH(3), -CH(2)C(6)H(5)) and its substitution reactions. Inorganic Chemistry, 49(4):1283-1285.

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Abstract

N-Alkylated derivatives of 1,3,5-triazacyclohexane (tach) are versatile, facially coordinating ligands. We present the syntheses and full characterization of two new complexes of the (R(3)tach)ReO3](+) type. In these complexes, the tach ligand is readily substituted by bi- and tridentate ligands; hence, they can be considered as sources of the ReO3](+) motif for Re-VII complexes.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
DDC:540 Chemistry
Language:English
Date:2010
Deposited On:23 Feb 2011 18:35
Last Modified:28 Nov 2013 01:06
Publisher:American Chemical Society
ISSN:0020-1669
Funders:Swiss National Science Foundation
Publisher DOI:10.1021/ic902114p
PubMed ID:20055461
Other Identification Number:ISI:000274240700005
Citations:Web of Science®. Times Cited: 5
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Scopus®. Citation Count: 6

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