Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-46624
Barman, S; Furukawa, H; Blacque, O; Venkatesan, K; Yaghi, O M; Berke, H (2010). Azulene based metal-organic frameworks for strong adsorption of H-2. Chemical Communications, 46(42):7981-7983.
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Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H-2 interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H-2 molecules in the framework.
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|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Deposited On:||23 Feb 2011 16:39|
|Last Modified:||27 Nov 2013 22:37|
|Publisher:||Royal Society of Chemistry|
|Other Identification Number:||ISI:000283260400033|
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