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Conceptual approach to the reactivity of dihydrogen


Berke, H (2010). Conceptual approach to the reactivity of dihydrogen. ChemPhysChem, 11(9):1837-1849.

Abstract

Dihydrogen reactions are mainly reaction-center-mediated. In a systematic approach, these reactions are divided into the steps of splitting of H-2 and H-atom transfers with homolytic and heterolytic splitting at mono- and dinuclear reaction centers, and further homopolar H transfers in Wilkinson-type hydrogenations (insertion and reductive elimination) and heteropolar transfers in ionic hydrogenations (hydride before proton, proton before hydride, simultaneous hydride/proton transfers). Based on these categories, transfer hydrogenations are also surveyed. A separate class of reactions is one-electron reactions of dihydrogen.

Dihydrogen reactions are mainly reaction-center-mediated. In a systematic approach, these reactions are divided into the steps of splitting of H-2 and H-atom transfers with homolytic and heterolytic splitting at mono- and dinuclear reaction centers, and further homopolar H transfers in Wilkinson-type hydrogenations (insertion and reductive elimination) and heteropolar transfers in ionic hydrogenations (hydride before proton, proton before hydride, simultaneous hydride/proton transfers). Based on these categories, transfer hydrogenations are also surveyed. A separate class of reactions is one-electron reactions of dihydrogen.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Date:June 2010
Deposited On:23 Feb 2011 15:33
Last Modified:05 Apr 2016 14:49
Publisher:Wiley-Blackwell
ISSN:1439-4235
Publisher DOI:https://doi.org/10.1002/cphc.200901014
PubMed ID:20518049
Other Identification Number:ISI:000279742800003
Permanent URL: https://doi.org/10.5167/uzh-46626

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