Semenov, S N; Taghipourian, S F; Blacque, O; Fox, T; Venkatesan, K; Berke, H (2010). An iron-capped metal−organic polyyne: {[Fe](C≡C)2[W]≡CC≡CC≡[W](C≡C)2[Fe]}. Journal of the American Chemical Society, 132(22):7584-7585.
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Abstract
The organometallic conjugated complex H(C C)(2)W] CC CC W](C C)(2)H containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.
| Other titles: | An iron-capped metal-organic polyyne: {[Fe](C[triple bond]C)2[W][triple bond]CC[triple bond]CC[triple bond][W](C[triple bond]C)2[Fe]} |
|---|---|
| Item Type: | Journal Article, refereed, original work |
| Communities & Collections: | 07 Faculty of Science > Institute of Inorganic Chemistry |
| DDC: | 540 Chemistry |
| Language: | English |
| Date: | 2010 |
| Deposited On: | 23 Feb 2011 18:35 |
| Last Modified: | 23 Nov 2012 14:12 |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| Publisher DOI: | 10.1021/ja102570f |
| PubMed ID: | 20465259 |
| Other Identification Number: | ISI:000278837100010 |
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