Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-48411
Garrett-Roe, S; Perakis, F; Rao, F; Hamm, P (2011). Three-dimensional infrared spectroscopy of isotope-substituted liquid water reveals heterogeneous dynamics. Journal of Physical Chemistry. B, 115(21):6976-6984.
The dynamics of the hydrogen bond network of
isotopically substituted liquid water are investigated with a new ultrafast nonlinear vibrational spectroscopy, three-dimensional infrared spectroscopy (3D-IR). The 3D-IR spectroscopy is sensitive to three-point frequency fluctuation correlation functions, and the measurements reveal heterogeneous structural relaxation dynamics. We interpret these results as subensembles of water which do not interconvert on a half picosecond time scale. We connect the experimental results to molecular dynamics
(MD) simulations, performing a line shape analysis as well as complex network analysis.
|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Institute of Physical Chemistry|
|Deposited On:||09 Sep 2011 14:24|
|Last Modified:||27 Nov 2013 22:33|
|Publisher:||American Chemical Society|
|Funders:||Swiss National Science Foundation (SNF) trough NCCR MUST, National Science Foundation (USA)|
|Additional Information:||This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry. B, copyright © American Chemical Society after peer review and technical editing by the publisher.|
|Citations:||Web of Science®. Times cited: 21|
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