Abstract

Three triorganotin(IV) complexes of composition R3SnLH (R = Me, Bu and Ph and LH = 2-[(E)-2-(4-hydroxy-3,5-dimethylphenyl)-1-diazenyl]benzoate) have been synthesized and characterized by 1H-,13C-, 119Sn- NMR, and IR spectroscopic techniques in combination with elemental analysis. The crystal structures of the carboxylate ligand HO2CC6H4-o in its neutral form and three triorganotin(IV) complexes, viz., polymeric (R3Sn[O2CC6H4-o])n (R = Me (1) and Bu (2)) and monomeric Ph3Sn[O2CC6H4-o] (3) complexes are reported. The polymeric complexes 1 and 2 exist as extended chains in which the LH-bridged Sn-atoms adopt a trans-R3SnO2 trigonal bipyramidal configuration with R groups in the equatorial positions and the axial sites occupied by an oxygen atom from the carboxylate ligand and the phenoxide O atom of the next carboxylate ligand. The Sn atom in complex 3 has a distorted tetrahedral geometry. In all three complexes, the carboxylate ligand is in the zwitterionic form with the phenolic proton moved to the nearby azo nitrogen atom, in contrast to the free carboxylic acid ligand which is in the azo form.