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Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-52582

Mavris, C; Plötze, M; Mirabella, A; Giaccai, D; Valboa, G; Egli, M (2011). Clay mineral evolution along a soil chronosequence in an Alpine proglacial area. Geoderma, 165(1):106-117.

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Abstract

As a consequence of global warming, additional areas will become ice-free and subject to weathering and soil formation. The most evident soil changes in the Alps will occur in proglacial areas where young soils will continuously develop due to glacier retreat. Little is known about the initial stages of weathering and soil formation, i.e. during the first decades of soil genesis. In this study, we investigated clay minerals formation during a time span 0–150 years in the proglacial area of Morteratsch (Swiss Alps). The soils developed on granitic till and were Lithic Leptosols.
Mineralogical measurements of the clay (< 2 μm) and fine silt fraction (2–32 μm) were carried out using XRD (X-ray Diffraction) and DRIFT (Diffuse Reflectance Infrared Fourier Transform). Fast formation and transformation mechanisms were measured in the clay fraction. The decreasing proportion of trioctahedral phases with time confirmed active chemical weathering. Since the start of soil formation, smectite was actively formed. Some smectite (low charge) and vermiculite (high charge) was however already present in the parent material. Main source of smectite formation was biotite, hornblende and probably plagioclase. Furthermore, irregularly and regularly interstratified clay minerals (mica–HIV or mica–vermiculite) were formed immediately after the start of moraine exposure to weathering. In addition, hydroxy-interlayered smectite (HIS) as a transitory weathering product from mica to smectite was detected. Furthermore, since the start of soil evolution, kaolinite was progressively formed. In the silt fraction, only little changes could be detected; i.e. some formation of an interstratified mica–HIV or mica–vermiculite phase.
The detected clay mineral formation and transformation mechanisms within this short time span confirmed the high reactivity of freshly exposed sediments, even in a cryic environment.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Institute of Geography
DDC:910 Geography & travel
Language:English
Date:2011
Deposited On:06 Dec 2011 14:11
Last Modified:27 Nov 2013 23:19
Publisher:Elsevier
ISSN:0016-7061
Publisher DOI:10.1016/j.geoderma.2011.07.010
Citations:Web of Science®. Times Cited: 5
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Scopus®. Citation Count: 8

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