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Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-56869

Mloston, G; Pieczonka, A M; Korany, A A; Linden, A; Heimgartner, H (2012). A new approach to morpholin-2-one derivatives via the reaction of β-amino alcohols with dicyanofumarates. ARKIVOC, 2012(iii):181-192.

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Abstract

A novel approach for the synthesis of morpholin-2-one derivatives from dialkyl dicyanofumarates and β-amino alcohols is presented. The reaction takes place under mild conditions via an addition-elimination-lactonization pathway. The formation of the six- membered ring occurs selectively leading to a single diastereomer. In contrast to arylhydrazines, the reaction of hydrazine hydrate with dicyanofumarates yields pyrazol-3(2H)-ones and not 5-aminopyrazoles.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
DDC:540 Chemistry
Language:English
Date:23 January 2012
Deposited On:02 Apr 2012 07:20
Last Modified:10 Jul 2014 21:13
Publisher:Arkat USA Inc
ISSN:1551-7004
Funders:European Social Fund ‘HUMAN – BEST INVESTMENT!’
Official URL:http://www.arkat-usa.org/get-file/42701
Citations:Google Scholar™
Scopus®. Citation Count: 2

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