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Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes


Barman, S; Furukawa, H; Blacque, O; Venkatesan, K; Yaghi, O M; Jin, G X; Berke, H (2011). Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes. Chemical Communications, 47(43):11882-11884.

Abstract

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metallinker complex as a precursor to construct MOF-648.

Abstract

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metallinker complex as a precursor to construct MOF-648.

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23 citations in Web of Science®
23 citations in Scopus®
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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2011
Deposited On:12 Mar 2012 17:26
Last Modified:05 Apr 2016 15:41
Publisher:Royal Society of Chemistry
ISSN:1359-7345
Publisher DOI:https://doi.org/10.1039/c1cc14387e
Other Identification Number:ISI:000296202800017

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