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Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-62021

Nikolaev, Vsevolod; Hennig, Lothar; Heimgartner, Heinz; Schulze, Bärbel; Nikolaev, Valerij (2006). Dual reactivity of imidic carbonyl ylides in Rh(II)-catalyzed reactions of alpha-diazocarbonyl compounds with succinimide. Tetrahedron Letters, 47(15):2643-2647.

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Abstract

Stabilization of imidic carbonyl ylides derived from alpha-diazocarbonyl compounds and succinimide occurs in two different ways: ylides from diazoesters experience a [1,4]-hydrogen shift to produce the corresponding O-alkylimidates while their analogues with at least one acyl group undergo [1,5]-electrocyclization yielding 1,3-dioxoles.

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Institute of Organic Chemistry
DDC:540 Chemistry
Language:English
Date:2006
Deposited On:22 May 2012 09:02
Last Modified:19 Apr 2014 10:53
Publisher:Elsevier
ISSN:0040-4039
Publisher DOI:10.1016/j.tetlet.2006.01.155
Citations:Web of Science®. Times Cited: 7
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