Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-62021
Nikolaev, Vsevolod; Hennig, Lothar; Heimgartner, Heinz; Schulze, Bärbel; Nikolaev, Valerij (2006). Dual reactivity of imidic carbonyl ylides in Rh(II)-catalyzed reactions of alpha-diazocarbonyl compounds with succinimide. Tetrahedron Letters, 47(15):2643-2647.
![[img]](http://www.zora.uzh.ch/style/images/fileicons/application_pdf.png) | Published Version PDF - Registered users only 133Kb | |
| Accepted Version 146Kb |
Abstract
Stabilization of imidic carbonyl ylides derived from alpha-diazocarbonyl compounds and succinimide occurs in two different ways: ylides from diazoesters experience a [1,4]-hydrogen shift to produce the corresponding O-alkylimidates while their analogues with at least one acyl group undergo [1,5]-electrocyclization yielding 1,3-dioxoles.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Institute of Organic Chemistry |
| DDC: | 540 Chemistry |
| Language: | English |
| Date: | 2006 |
| Deposited On: | 22 May 2012 09:02 |
| Last Modified: | 17 May 2013 11:56 |
| Publisher: | Elsevier |
| ISSN: | 0040-4039 |
| Publisher DOI: | 10.1016/j.tetlet.2006.01.155 |
| WoS Citation Count: | 6 |
Users (please log in): suggest update or correction for this item
Repository Staff Only: item control page
