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Tricarbonyltris(pyrazol-1-yl)methanesulfonato-kappa N-3,N `,N `'] rhenium(I) acetone solvate


Kunz, Peter; Kurz, Philipp; Spingler, Bernhard; Alberto, Roger (2007). Tricarbonyltris(pyrazol-1-yl)methanesulfonato-kappa N-3,N `,N `'] rhenium(I) acetone solvate. Acta Crystallographica. Section E, Structure Reports Online, 63(Part 2):M363-M364.

Abstract

The title compound, Re(C10H9N6O3S)(CO)(3)]center dot C3H6O, was prepared in almost quantitative yield by reaction of Re(CO)(5)Br with the thallium salt of the tris( pyrazolyl) methanesulfonate (tpms) ligand. It shows a slightly distorted octahedral geometry for the fac-Re( CO)(3)N-3 unit, with the ligand forming three six-membered N-bonded chelate rings. AC-H center dot center dot center dot O interaction between the main molecule and the solvent molecule helps to establish the crystal packing.

The title compound, Re(C10H9N6O3S)(CO)(3)]center dot C3H6O, was prepared in almost quantitative yield by reaction of Re(CO)(5)Br with the thallium salt of the tris( pyrazolyl) methanesulfonate (tpms) ligand. It shows a slightly distorted octahedral geometry for the fac-Re( CO)(3)N-3 unit, with the ligand forming three six-membered N-bonded chelate rings. AC-H center dot center dot center dot O interaction between the main molecule and the solvent molecule helps to establish the crystal packing.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:February 2007
Deposited On:23 Oct 2012 12:46
Last Modified:05 Apr 2016 16:01
Publisher:Wiley-Blackwell
ISSN:1600-5368
Publisher DOI:https://doi.org/10.1107/S1600536806055942
Other Identification Number:ISI:000245187300044
Permanent URL: https://doi.org/10.5167/uzh-65727

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