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1D-and 2D-architectures via self-assembly of the novel sandwich-type polyoxometalate Zn2Sb2(B-alpha-ZnW9O34)(2)](14-)


Ni, L; Patzke, G R (2012). 1D-and 2D-architectures via self-assembly of the novel sandwich-type polyoxometalate Zn2Sb2(B-alpha-ZnW9O34)(2)](14-). CrystEngComm, 14(20):6778-6782.

Abstract

Two novel 1D and 2D polyoxometalate (POM) frameworks based on the new Zn2Sb2(B-alpha-ZnW9O34)(2)](14-) building block were selectively obtained from one-pot transformations of the trilacunary Keggin-type B-alpha-SbW9O33](9-) precursor via Sb/Zn exchange, followed by self-assembly of the sandwich-type polyanions. The compounds were characterized in detail with a wide range of analytical methods, including single crystal and powder X-ray diffraction, thermogravimetric analysis and various spectroscopic techniques, and their photoluminescence properties were investigated at room temperature. Electrochemical behavior of the 1D and 2D {Zn2Sb2}-based POMs was characterized by means of cyclic voltammetry (CV) in sodium acetate buffer solution. Both compounds are effective catalysts for the oxidation of cyclohexanol with hydrogen peroxide.

Abstract

Two novel 1D and 2D polyoxometalate (POM) frameworks based on the new Zn2Sb2(B-alpha-ZnW9O34)(2)](14-) building block were selectively obtained from one-pot transformations of the trilacunary Keggin-type B-alpha-SbW9O33](9-) precursor via Sb/Zn exchange, followed by self-assembly of the sandwich-type polyanions. The compounds were characterized in detail with a wide range of analytical methods, including single crystal and powder X-ray diffraction, thermogravimetric analysis and various spectroscopic techniques, and their photoluminescence properties were investigated at room temperature. Electrochemical behavior of the 1D and 2D {Zn2Sb2}-based POMs was characterized by means of cyclic voltammetry (CV) in sodium acetate buffer solution. Both compounds are effective catalysts for the oxidation of cyclohexanol with hydrogen peroxide.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2012
Deposited On:05 Mar 2013 12:34
Last Modified:05 Apr 2016 16:36
Publisher:R S C Publications
ISSN:1466-8033
Publisher DOI:https://doi.org/10.1039/C2CE25319D

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