Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-8674
Cervetto, V; Hamm, P; Helbing, J (2008). Transient 2D-IR spectroscopy of thiopeptide isomerization. Journal of Physical Chemistry. B, 112(28):8398-8405.
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Transient 2D-IR spectra have been recorded during the photoreaction of the thioxopeptide Boc-Ala-Gly(=S)-Ala-Aib-OMe. We demonstrate the potential of transient 2D-IR spectroscopy to resolve vibrational bands hidden in conventional pump−probe spectra. Different types of transient cross-peak signals are observed, and their information content is discussed by comparison with model spectra.
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|Item Type:||Journal Article, refereed, original work|
|Communities & Collections:||07 Faculty of Science > Department of Chemistry|
|Date:||17 July 2008|
|Deposited On:||15 Jan 2009 11:09|
|Last Modified:||05 Jun 2014 13:50|
|Publisher:||American Chemical Society|
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