Permanent URL to this publication: http://dx.doi.org/10.5167/uzh-8797
Palomo, C; Oiarbide, M; García, J M; Bañuelos, P; Odriozola, J M; Razkin, J; Linden, A (2008). Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers. Organic Letters, 10(13):2637-2640.
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Abstract
A camphor-based alpha'-hydroxy enone reagent acts as a chiral acrylate equivalent in copper-catalyzed Michael reactions of beta-keto esters and affords products that possess all-carbon quaternary stereocenters of high enantiomeric purity.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Institute of Organic Chemistry |
| DDC: | 540 Chemistry |
| Language: | English |
| Date: | 2008 |
| Deposited On: | 19 Jan 2009 17:03 |
| Last Modified: | 23 Nov 2012 15:39 |
| Publisher: | American Chemical Society |
| ISSN: | 1523-7052 |
| Funders: | Universidad del Paı´s Vasco, Gobierno Vasco, MEC, UPNA |
| Publisher DOI: | 10.1021/ol800564d |
| PubMed ID: | 18517215 |
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