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Through-space interactions in enshroudedm-terphenylsilanes


Romanato, Paola; Duttwyler, Simon; Linden, Anthony; Baldridge, Kim K; Siegel, Jay S (2014). Through-space interactions in enshroudedm-terphenylsilanes. Journal of Physical Organic Chemistry, 27(4):277-283.

Abstract

A series of m-terphenyl-substituted silanes was prepared and studied with regard to the steric and electronic interactions between the silyl core and the terphenyl shroud. Only weak conformational preferences were observed for the core, but the π-basicity of the lateral rings led to distinct nuclear magnetic resonance shifts, and o-fluorine atoms led to through-space coupling effects.

Abstract

A series of m-terphenyl-substituted silanes was prepared and studied with regard to the steric and electronic interactions between the silyl core and the terphenyl shroud. Only weak conformational preferences were observed for the core, but the π-basicity of the lateral rings led to distinct nuclear magnetic resonance shifts, and o-fluorine atoms led to through-space coupling effects.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2014
Deposited On:06 Nov 2014 15:15
Last Modified:05 Apr 2016 18:28
Publisher:Wiley-Blackwell Publishing, Inc.
ISSN:0894-3230
Funders:Swiss National Science Foundation
Publisher DOI:https://doi.org/10.1002/poc.3265

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