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Der massenspektrometrische Zerfall von Tetralin-Derivaten. Beitrag zur massenspektrometrischen Retro-Diels-AIder Reaktion


Heimgartner, Heinz; Weibel, Peter A; Hesse, Manfred (1974). Der massenspektrometrische Zerfall von Tetralin-Derivaten. Beitrag zur massenspektrometrischen Retro-Diels-AIder Reaktion. Helvetica Chimica Acta, 57(6):1510-1519.

Abstract

The mass spectral decomposition of the 1-tetralol derivatives 2, 3 and 4 in view of the retro Diels-Alder reaction is investigated, for which deuterated derivatives, high resolution data and metastable peaks were used. By these studies it follows that the decyclisation reaction on ring A possesses the character of a retro Diels-Alder reaction only in some part. The main mass spectral degradation is forced by the substituents placed thereon.

Abstract

The mass spectral decomposition of the 1-tetralol derivatives 2, 3 and 4 in view of the retro Diels-Alder reaction is investigated, for which deuterated derivatives, high resolution data and metastable peaks were used. By these studies it follows that the decyclisation reaction on ring A possesses the character of a retro Diels-Alder reaction only in some part. The main mass spectral degradation is forced by the substituents placed thereon.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:German
Date:1974
Deposited On:01 Dec 2014 16:13
Last Modified:05 Apr 2016 18:33
Publisher:Wiley-Blackwell Publishing, Inc.
ISSN:0018-019X
Funders:Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung

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