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Activation of [$^{99(m)}$TcO$_4$]− by phosphonium cations


Braband, Henrik; Benz, Michael; Tooyama, Yuji; Alberto, Roger (2014). Activation of [$^{99(m)}$TcO$_4$]− by phosphonium cations. Chemical Communications, 50(31):4126-4129.

Abstract

Phosphonium salts in solution or bound to solid phase supports interact with the robust [$^{99(m)}$TcO$_4$]− anion in neutral water. This activated form of [$^{99(m)}$TcO$_4$]− represents a source for complexes with the fac-{$^{99(m)}$Tc$^{VII}$O$_3$}+ core, which can be synthesized in high yields and purity.

Abstract

Phosphonium salts in solution or bound to solid phase supports interact with the robust [$^{99(m)}$TcO$_4$]− anion in neutral water. This activated form of [$^{99(m)}$TcO$_4$]− represents a source for complexes with the fac-{$^{99(m)}$Tc$^{VII}$O$_3$}+ core, which can be synthesized in high yields and purity.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2014
Deposited On:20 Feb 2015 09:53
Last Modified:05 Apr 2016 18:56
Publisher:RSC Publishing
ISSN:1359-7345
Publisher DOI:https://doi.org/10.1039/c4cc00718b

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