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Metal-free triplet phosphors with high emission efficiency and high tunability


Koch, Michael; Perumal, Karthikeyan; Blacque, Olivier; Garg, Jai Anand; Saiganesh, Ramanathan; Kabilan, Senthamaraikannan; Balasubramanian, Kallupattu Kuppusamy; Venkatesan, Koushik (2014). Metal-free triplet phosphors with high emission efficiency and high tunability. Angewandte Chemie Internationale Edition, 53(25):6378-6382.

Abstract

Design of highly efficient phosphorescent emitters based on metal- and heavy atom-free boron compounds has been demonstrated by taking advantage of the singlet fission process. The combination of a suitable molecular scaffold and appropriate electronic nature of the substituents has been utilized to tailor the phosphorescence emission properties in solution, neat solid, and in doped PMMA thin films.

Abstract

Design of highly efficient phosphorescent emitters based on metal- and heavy atom-free boron compounds has been demonstrated by taking advantage of the singlet fission process. The combination of a suitable molecular scaffold and appropriate electronic nature of the substituents has been utilized to tailor the phosphorescence emission properties in solution, neat solid, and in doped PMMA thin films.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:June 2014
Deposited On:20 Feb 2015 10:12
Last Modified:08 Dec 2017 11:09
Publisher:Wiley-VCH Verlag
ISSN:1433-7851
Publisher DOI:https://doi.org/10.1002/anie.201402199

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