Header

UZH-Logo

Maintenance Infos

Bubble evolution and properties in homogeneous nucleation simulations


Angélil, Raymond; Diemand, Jürg; Tanaka, Kyoko K; Tanaka, Hidekazu (2014). Bubble evolution and properties in homogeneous nucleation simulations. Physical Review E (Statistical, Nonlinear, and Soft Matter Physics), 90(6):online.

Abstract

We analyze the properties of naturally formed nanobubbles in Lennard-Jones molecular dynamics simulations of liquid-to-vapor nucleation in the boiling and the cavitation regimes. The large computational volumes provide a realistic environment at unchanging average temperature and liquid pressure, which allows us to accurately measure properties of bubbles from their inception as stable, critically sized bubbles, to their continued growth into the constant speed regime. Bubble gas densities are up to 50 % lower than the equilibrium vapor densities at the liquid temperature, yet quite close to the gas equilibrium density at the lower gas temperatures measured in the simulations: The latent heat of transformation results in bubble gas temperatures up to 25 % below those of the surrounding bulk liquid. In the case of rapid bubble growth—typical for the cavitation regime—compression of the liquid outside the bubble leads to local temperature increases of up to 5 %, likely significant enough to alter the surface tension as well as the local viscosity. The liquid-vapor bubble interface is thinner than expected from planar coexistence simulations by up to 50 % . Bubbles near the critical size are extremely nonspherical, yet they quickly become spherical as they grow. The Rayleigh-Plesset description of bubble-growth gives good agreement in the cavitation regime.

Abstract

We analyze the properties of naturally formed nanobubbles in Lennard-Jones molecular dynamics simulations of liquid-to-vapor nucleation in the boiling and the cavitation regimes. The large computational volumes provide a realistic environment at unchanging average temperature and liquid pressure, which allows us to accurately measure properties of bubbles from their inception as stable, critically sized bubbles, to their continued growth into the constant speed regime. Bubble gas densities are up to 50 % lower than the equilibrium vapor densities at the liquid temperature, yet quite close to the gas equilibrium density at the lower gas temperatures measured in the simulations: The latent heat of transformation results in bubble gas temperatures up to 25 % below those of the surrounding bulk liquid. In the case of rapid bubble growth—typical for the cavitation regime—compression of the liquid outside the bubble leads to local temperature increases of up to 5 %, likely significant enough to alter the surface tension as well as the local viscosity. The liquid-vapor bubble interface is thinner than expected from planar coexistence simulations by up to 50 % . Bubbles near the critical size are extremely nonspherical, yet they quickly become spherical as they grow. The Rayleigh-Plesset description of bubble-growth gives good agreement in the cavitation regime.

Statistics

Citations

4 citations in Web of Science®
5 citations in Scopus®
Google Scholar™

Altmetrics

Downloads

47 downloads since deposited on 24 Feb 2015
12 downloads since 12 months
Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Institute for Computational Science
Dewey Decimal Classification:530 Physics
Language:English
Date:2014
Deposited On:24 Feb 2015 09:29
Last Modified:19 Dec 2017 04:54
Publisher:American Physical Society
ISSN:1539-3755
Publisher DOI:https://doi.org/10.1103/PhysRevE.90.063301

Download

Download PDF  'Bubble evolution and properties in homogeneous nucleation simulations'.
Preview
Content: Accepted Version
Filetype: PDF
Size: 1MB
View at publisher