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New Reactions of Sulfur-Centered 1,3-Dipoles Generated from Thioketones in Three-Component Reactions with Phenyl Azide and an Electron-Deficient Dipolarophile


Mloston, Grzegorz; Romanski, Jaroslaw; Heimgartner, Heinz (1997). New Reactions of Sulfur-Centered 1,3-Dipoles Generated from Thioketones in Three-Component Reactions with Phenyl Azide and an Electron-Deficient Dipolarophile. Phosphorus, Sulfur and Silicon and the Related Elements, 120&121:463-464.

Abstract

Reactions of cycloaliphatic thioketones with phenyl azide in the presence of an electron-deficient C-C-dipolarophile have been studied. It was shown that the course of the reactions and the structure of the products depend strongly on the type of the dipolarophile used. Only in the case of fumaronitrile the interception product of the intermediate thiocarbonyl-S-imide was obtained.

Abstract

Reactions of cycloaliphatic thioketones with phenyl azide in the presence of an electron-deficient C-C-dipolarophile have been studied. It was shown that the course of the reactions and the structure of the products depend strongly on the type of the dipolarophile used. Only in the case of fumaronitrile the interception product of the intermediate thiocarbonyl-S-imide was obtained.

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Additional indexing

Item Type:Journal Article, refereed, further contribution
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:1997
Deposited On:06 Aug 2015 10:24
Last Modified:08 Dec 2017 13:44
Publisher:Taylor & Francis Inc.
ISSN:1042-6507
Funders:Polish State Committee for Scientific Research, Swiss National Science Foundation

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