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Single molecule magnet behaviour in a rare trinuclear {CrIIIDyIII2} methoxo-bridged complex


Car, Pierre-Emmanuel; Favre, Annaïck; Caneschi, Andrea; Sessoli, Roberta (2015). Single molecule magnet behaviour in a rare trinuclear {CrIIIDyIII2} methoxo-bridged complex. Dalton Transactions, 44(36):15769-15773.

Abstract

The reaction of the chromium(III) chloride tetrahydrofuran complex with the dipivaloylmethane ligand, the lanthanide alcoholic salt DyCl3·CH3OH and the 1,1,1-tris(hydroxymethyl)-ethane ligand resulted in the formation of a new trinuclear chromium–dysprosium complex. Magnetic investigations revealed that the new 3d–4f complex exhibits single molecule magnet behaviour.

Abstract

The reaction of the chromium(III) chloride tetrahydrofuran complex with the dipivaloylmethane ligand, the lanthanide alcoholic salt DyCl3·CH3OH and the 1,1,1-tris(hydroxymethyl)-ethane ligand resulted in the formation of a new trinuclear chromium–dysprosium complex. Magnetic investigations revealed that the new 3d–4f complex exhibits single molecule magnet behaviour.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:28 September 2015
Deposited On:13 Jan 2016 15:56
Last Modified:05 Apr 2016 19:53
Publisher:Royal Society of Chemistry
ISSN:1477-9226
Publisher DOI:https://doi.org/10.1039/c5dt02459e

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