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Solvent-free synthesis of bis(2,2′:6′,2′′-terpyridin-4′-yl)amine and its metal complexes


Fallahpour, R A (2008). Solvent-free synthesis of bis(2,2′:6′,2′′-terpyridin-4′-yl)amine and its metal complexes. Synthesis, (10):1514-1516.

Abstract

The key compound bis(2,2′:6′,2′′-terpyridin-4′-yl)amine was prepared in one step starting from 4′-amino-2,2′:6′,2′′-terpyridine and 4′-bromo-2,2′:6′,2′′-terpyridine in quantitative yield. In addition, we have established an easy and efficient route for the synthesis of the bromoterpyridine compound. Using the novel ligand, two ruthenium complexes were also prepared.

Abstract

The key compound bis(2,2′:6′,2′′-terpyridin-4′-yl)amine was prepared in one step starting from 4′-amino-2,2′:6′,2′′-terpyridine and 4′-bromo-2,2′:6′,2′′-terpyridine in quantitative yield. In addition, we have established an easy and efficient route for the synthesis of the bromoterpyridine compound. Using the novel ligand, two ruthenium complexes were also prepared.

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Additional indexing

Item Type:Journal Article, refereed, further contribution
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:May 2008
Deposited On:15 Feb 2009 11:15
Last Modified:06 Dec 2017 17:49
Publisher:Thieme
ISSN:0039-7881
Publisher DOI:https://doi.org/10.1055/s-2008-1072574

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