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Tunable photochemical/redox properties of (phenylthio)ncorannulenes: application to a photovoltaic device


Steinauer, Angela; Butterfield, Anna M; Linden, Anthony; Molina-Ontario, Agustin; Buck, David C; Cotta, Robert W; Echegoyen, Luis; Baldridge, Kim K; Siegel, Jay S (2016). Tunable photochemical/redox properties of (phenylthio)ncorannulenes: application to a photovoltaic device. Journal of the Brazilian Chemical Society, 27(10):1866-1871.

Abstract

The additive substituent effect of phenylmercapto derivatives of corannulene are investigated by spectroscopic, electrochemical, and computational techniques. The per-substituted phenylmercaptocorannulene is incorporated as a replacement for [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a photovoltaic device.

Abstract

The additive substituent effect of phenylmercapto derivatives of corannulene are investigated by spectroscopic, electrochemical, and computational techniques. The per-substituted phenylmercaptocorannulene is incorporated as a replacement for [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a photovoltaic device.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2016
Deposited On:08 Dec 2016 13:24
Last Modified:28 Apr 2017 05:42
Publisher:Sociedade Brasileira de Química, SBQ
ISSN:0103-5053
Funders:University of Zurich, Swiss National Science Foundation, Robert A. Welch Foundation (endowed chair, grant #AH-0033, L. E.), US National Science Fundation (NSF), grants: DMR-1205302 (PREM Program) and CHE-1408865 (L. E., A. M.-O., D. C. B., R. W. C.), National Basic Research Program of China 2015CB856500 (K. K. B., J. S. S.), Qian Ren Scholar Program of China (K. K. B., J. S. S.), Synergetic Innovation Center of Chemical Science and Engineering, Tianjin (K. K. B., J. S. S.)
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.5935/0103-5053.20160072

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