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Bis[1,2-bis(dimethylphosphino)ethane]dichloridonitrosyltungsten(0) chloride


Avramovic, N; Blacque, O; Schmalle, H W; Berke, H (2008). Bis[1,2-bis(dimethylphosphino)ethane]dichloridonitrosyltungsten(0) chloride. Acta Crystallographica. Section E, Structure Reports Online, 64(1):M245.

Abstract

In the crystal structure of the title compound, [WCl2(NO)(C6H16P2)2]Cl, the seven-coordinated tungsten(II) center displays a distorted pentagonal-bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.

Abstract

In the crystal structure of the title compound, [WCl2(NO)(C6H16P2)2]Cl, the seven-coordinated tungsten(II) center displays a distorted pentagonal-bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Uncontrolled Keywords:Key indicators: single-crystal X-ray study; T = 183 K; mean (C–C) = 0.007 A°; disorder in main residue; R factor = 0.025; wR factor = 0.060; data-to-parameter ratio = 18.1.
Language:English
Date:2008
Deposited On:15 Feb 2009 12:41
Last Modified:06 Dec 2017 17:55
Publisher:Wiley-Blackwell
ISSN:1600-5368
Publisher DOI:https://doi.org/10.1107/S1600536807067128

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