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Bis(glycinato-kappa2N,O)dinitrosylmolybdenum(0) and bis(2-aminoethanethiolato-kappa2N,S)dinitrosylmolybdenum(0) acetonitrile monosolvate


Bucher, J; Blacque, O; Schmalle, H W; Berke, H (2008). Bis(glycinato-kappa2N,O)dinitrosylmolybdenum(0) and bis(2-aminoethanethiolato-kappa2N,S)dinitrosylmolybdenum(0) acetonitrile monosolvate. Acta Crystallographica. Section C, Crystal Structure Communications, 64(2):M87-M90.

Abstract

The title compds., [Mo(C2H4NO2)2(NO)2], (I), and [Mo(C2H6NS)2(NO)2]CH3CN, (II), contain distorted octahedral complexes in which the monoanionic N,S- and N,O-bidentate ligands coordinate the molybdenum centers in different modes. The anionic O atoms of the glycinate ligands in (I) are coordinated trans to the nitrosyl ligands and the amine N atoms are located trans to each other, whereas in (II) the anionic S atoms are coordinated trans to each other and the amine N atoms are located trans to the nitrosyl ligands. Each compd. has a single complete complex in the asym. unit on a general position. Six N-HO contacts with NO distances of less than 3.2 .ANG. are obsd. in (I) between the amine groups and the nitrosyl and carboxylate O atoms. In the 1:1 solvate (II), the acetonitrile mol. forms short N-HN contacts (NN < 3.2 .ANG.) between the solvent N atoms and one of the amine H atoms. In addn., three weak intermol. N-HS interactions (NS > 3.3 .ANG.) contribute to the stabilization of the structure of (II)

Abstract

The title compds., [Mo(C2H4NO2)2(NO)2], (I), and [Mo(C2H6NS)2(NO)2]CH3CN, (II), contain distorted octahedral complexes in which the monoanionic N,S- and N,O-bidentate ligands coordinate the molybdenum centers in different modes. The anionic O atoms of the glycinate ligands in (I) are coordinated trans to the nitrosyl ligands and the amine N atoms are located trans to each other, whereas in (II) the anionic S atoms are coordinated trans to each other and the amine N atoms are located trans to the nitrosyl ligands. Each compd. has a single complete complex in the asym. unit on a general position. Six N-HO contacts with NO distances of less than 3.2 .ANG. are obsd. in (I) between the amine groups and the nitrosyl and carboxylate O atoms. In the 1:1 solvate (II), the acetonitrile mol. forms short N-HN contacts (NN < 3.2 .ANG.) between the solvent N atoms and one of the amine H atoms. In addn., three weak intermol. N-HS interactions (NS > 3.3 .ANG.) contribute to the stabilization of the structure of (II)

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Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:February 2008
Deposited On:15 Feb 2009 12:31
Last Modified:21 Nov 2017 13:57
Publisher:Wiley-Blackwell
ISSN:0108-2701
Publisher DOI:https://doi.org/10.1107/S0108270107065584
Related URLs:http://journals.iucr.org/c/issues/2008/02/00/sq3117/sq3117bdy.html
PubMed ID:18252994

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