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Chemistry of chromium bis-acetylide complexes


Lopez-Hernandez, A; Venkatesan, K; Schmalle, H W; Berke, H (2009). Chemistry of chromium bis-acetylide complexes. Monatshefte für Chemie / Chemical Monthly, 140(7 ):845-857.

Abstract

Stable paramagnetic Cr(II) and Cr(III) bis(alkynyl) complexes of the type [trans(RC≡C)2Cr(dmpe)2] n+ (R = Ph, SiMe3, SiEt3, C≡C–SiMe3 n = 0, 1) were prepared and characterised by NMR, cyclic voltammetry, EPR, magnetic measurements, and X-ray single-crystal diffraction studies

Abstract

Stable paramagnetic Cr(II) and Cr(III) bis(alkynyl) complexes of the type [trans(RC≡C)2Cr(dmpe)2] n+ (R = Ph, SiMe3, SiEt3, C≡C–SiMe3 n = 0, 1) were prepared and characterised by NMR, cyclic voltammetry, EPR, magnetic measurements, and X-ray single-crystal diffraction studies

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Uncontrolled Keywords:Alkynes - Magnetic properties - Molecular wires - Oligomers - X-ray structure determination
Language:English
Date:July 2009
Deposited On:01 Jul 2009 07:14
Last Modified:05 Apr 2016 12:59
Publisher:Springer
ISSN:0026-9247
Additional Information:The original publication is available at www.springerlink.com
Publisher DOI:https://doi.org/10.1007/s00706-008-0094-2
Official URL:http://www.springerlink.com/content/82913665v774185l/

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