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Tetraethylammonium tricarbonylchlorido(isoquinoline-1-carboxylato-[kappa]2N,O)technetate(I)


Schmalle, H W; Alberto, R (2008). Tetraethylammonium tricarbonylchlorido(isoquinoline-1-carboxylato-[kappa]2N,O)technetate(I). Acta Crystallographica. Section E, Structure Reports Online, 64(9):m1213-m1214.

Abstract

The asymmetric unit of the title compound, (C8H20N)[Tc(C10H6NO2)Cl(CO)3], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetraethylammonium cations. The Tc atoms have slightly distorted octahedral coordination geometries, and they are linked with the cations by intermolecular C-H...O and C-H...Cl hydrogen-bonding contacts, forming two-dimensional columns, which lie approximately parallel to (001) in the crystal structure. The isochinolate (isoquinoline-1-carboxylate) ligands link the columns by partial [pi]-[pi] stacking [centroid-centroid distance 4.3733 (11) Å], forming a three-dimensional network structure.

Abstract

The asymmetric unit of the title compound, (C8H20N)[Tc(C10H6NO2)Cl(CO)3], consists of two crystallographically independent technetium complexes related via a pseudo-inversion centre and two tetraethylammonium cations. The Tc atoms have slightly distorted octahedral coordination geometries, and they are linked with the cations by intermolecular C-H...O and C-H...Cl hydrogen-bonding contacts, forming two-dimensional columns, which lie approximately parallel to (001) in the crystal structure. The isochinolate (isoquinoline-1-carboxylate) ligands link the columns by partial [pi]-[pi] stacking [centroid-centroid distance 4.3733 (11) Å], forming a three-dimensional network structure.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:September 2008
Deposited On:02 Mar 2009 11:10
Last Modified:05 Apr 2016 13:03
Publisher:Wiley-Blackwell
ISSN:1600-5368
Publisher DOI:https://doi.org/10.1107/S160053680802713X
Related URLs:http://journals.iucr.org/e/issues/2008/09/00/hb2781/hb2781bdy.html

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