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Influence of remote asymmetric centers in reversible encapsulation complexes


Schramm, Michael P; Restorp, Per; Zelder, Felix; Rebek, Julius Jr (2008). Influence of remote asymmetric centers in reversible encapsulation complexes. Journal of the American Chemical Society, 130(8):2450-2451.

Abstract

Reversible coencapsulation provides a means of fixing the orientation, increasing the effective concentration and expanding the time scale on which small molecules can interact. These features allowed us to look beyond steric asymmetric interactions. Isopropanol and other small molecules can sense the handedness of a remote asymmetric center even in the presence of a local one.

Abstract

Reversible coencapsulation provides a means of fixing the orientation, increasing the effective concentration and expanding the time scale on which small molecules can interact. These features allowed us to look beyond steric asymmetric interactions. Isopropanol and other small molecules can sense the handedness of a remote asymmetric center even in the presence of a local one.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:February 2008
Deposited On:20 Feb 2009 18:45
Last Modified:18 Feb 2018 10:57
Publisher:American Chemical Society
ISSN:0002-7863
OA Status:Closed
Publisher DOI:https://doi.org/10.1021/ja076162d
PubMed ID:18254625

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