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Photocorrosion-resistant Sb2Se3 photocathodes with earth abundant MoSx hydrogen evolution catalyst


Prabhakar, Rajiv Ramanujam; Septina, Wilman; Siol, Sebastian; Moehl, Thomas; Wick-Joliat, René; Tilley, S David (2017). Photocorrosion-resistant Sb2Se3 photocathodes with earth abundant MoSx hydrogen evolution catalyst. Journal of Materials Chemistry A, 5(44):23139-23145.

Abstract

The poor stability of high efficiency photoabsorber materials in aqueous media is one factor holding back the realization of photoelectrochemical (PEC) water splitting for large scale, practical solar fuels generation. Here, we demonstrate that highly efficient thin film Sb2Se3 – fabricated by a simple, low temperature selenization of electrodeposited Sb – is intrinsically stable towards photocorrosion in strongly acidic media (1 M H2SO4). Coupling with a photoelectrodeposited MoSx hydrogen evolution catalyst gives high photocurrents (5 mA cm−2 at 0 V vs. RHE) and high stability without protective layers. A low temperature sulfurization of the Sb2Se3–MoSx stack dramatically improved the onset potential, resulting in high photocurrent densities up to ∼16 mA cm−2 at 0 V vs. RHE. The simplicity with which these photocathodes are fabricated, combined with the high photocurrents and stability, make Sb2Se3 a strong candidate for scalable PEC cells.

Abstract

The poor stability of high efficiency photoabsorber materials in aqueous media is one factor holding back the realization of photoelectrochemical (PEC) water splitting for large scale, practical solar fuels generation. Here, we demonstrate that highly efficient thin film Sb2Se3 – fabricated by a simple, low temperature selenization of electrodeposited Sb – is intrinsically stable towards photocorrosion in strongly acidic media (1 M H2SO4). Coupling with a photoelectrodeposited MoSx hydrogen evolution catalyst gives high photocurrents (5 mA cm−2 at 0 V vs. RHE) and high stability without protective layers. A low temperature sulfurization of the Sb2Se3–MoSx stack dramatically improved the onset potential, resulting in high photocurrent densities up to ∼16 mA cm−2 at 0 V vs. RHE. The simplicity with which these photocathodes are fabricated, combined with the high photocurrents and stability, make Sb2Se3 a strong candidate for scalable PEC cells.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
08 University Research Priority Programs > Solar Light to Chemical Energy Conversion
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2017
Deposited On:08 Feb 2018 11:18
Last Modified:19 Feb 2018 10:53
Publisher:Royal Society of Chemistry
ISSN:2050-7488
OA Status:Closed
Publisher DOI:https://doi.org/10.1039/C7TA08993G

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