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Diazenide and hydrazide(2-) derivatives of the [Re(CO)3]+ core.


Alberto, R; Cowley, A R; Dilworth, J R; Donnelly, P S; Pratt, J (2004). Diazenide and hydrazide(2-) derivatives of the [Re(CO)3]+ core. Dalton Transactions, 17:2610-2611.

Abstract

Reaction of [ReBr3(CO)3]2- with aryldiazonium salts gives the Re(iii) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]-. The attachment of a PhNHCS tethering group to pyridyl hydrazine generates a HYNIC related proligand which gives a stable chelated pyridyliumthiocarbazide(2-) derivative of the [Re(I)(CO)3]+ core.

Abstract

Reaction of [ReBr3(CO)3]2- with aryldiazonium salts gives the Re(iii) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]-. The attachment of a PhNHCS tethering group to pyridyl hydrazine generates a HYNIC related proligand which gives a stable chelated pyridyliumthiocarbazide(2-) derivative of the [Re(I)(CO)3]+ core.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:7 September 2004
Deposited On:11 Feb 2008 12:25
Last Modified:05 Apr 2016 12:20
Publisher:Royal Society of Chemistry
ISSN:1477-9226
Publisher DOI:https://doi.org/10.1039/B407708C
PubMed ID:15514740

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