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Synthesis and Structures of Two Triorganotin(IV) Polymers R3Sn{O2CC6H4[N=C(H)}{C(CH3)CH(CH3)-3-OH]-p}n (R = Me and Ph) Containing a 4-[(2Z)-(3-Hydroxy-1-methyl-2-butenylidene)amino] benzoic Acid Framework


Basu Baul, T S; Masharing, C; Ruisi, G; Pettinari, C; Linden, A (2009). Synthesis and Structures of Two Triorganotin(IV) Polymers R3Sn{O2CC6H4[N=C(H)}{C(CH3)CH(CH3)-3-OH]-p}n (R = Me and Ph) Containing a 4-[(2Z)-(3-Hydroxy-1-methyl-2-butenylidene)amino] benzoic Acid Framework. Journal of Inorganic and Organometallic Polymers and Materials, 19(3):395-400.

Abstract

Two new polymeric triorganotin(IV) complexes
R3Sn{O2CC6H4[N=C(H)}{C(CH3)CH(CH3)-3-OH]-p}n
([Me3Sn(LH)]n: 1) and([Ph3Sn(LH)]n: 2) containing a 4-[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)amino]benzoate (LH) framework were prepared.Both compounds have been characterized by 1H, 13C, 119Sn NMR, IR and 119Sn Mossbauer spectroscopic techniques in combination with elemental analyses. The crystal structures of complexes 1 and 2 reveal that they exist as polymeric zig-zag chains in which the LH-bridged Sn-atoms adopt a trans-R3SnO2 trigonal bipyramidal configuration with R groups in the equatorial positions and the axial sites occupied by an oxygen atom from the carboxylate ligand and the alcoholic oxygen atom of the next carboxylate ligand in the chain. The carboxylate
ligands coordinate in the zwitterionic form with the alcoholic proton moved to the nearby nitrogen atom.

Abstract

Two new polymeric triorganotin(IV) complexes
R3Sn{O2CC6H4[N=C(H)}{C(CH3)CH(CH3)-3-OH]-p}n
([Me3Sn(LH)]n: 1) and([Ph3Sn(LH)]n: 2) containing a 4-[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)amino]benzoate (LH) framework were prepared.Both compounds have been characterized by 1H, 13C, 119Sn NMR, IR and 119Sn Mossbauer spectroscopic techniques in combination with elemental analyses. The crystal structures of complexes 1 and 2 reveal that they exist as polymeric zig-zag chains in which the LH-bridged Sn-atoms adopt a trans-R3SnO2 trigonal bipyramidal configuration with R groups in the equatorial positions and the axial sites occupied by an oxygen atom from the carboxylate ligand and the alcoholic oxygen atom of the next carboxylate ligand in the chain. The carboxylate
ligands coordinate in the zwitterionic form with the alcoholic proton moved to the nearby nitrogen atom.

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Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Uncontrolled Keywords:Organometallic polymers, Triorganotin carboxylates, NMR, Mossbauer, Crystal structure
Language:English
Date:September 2009
Deposited On:11 Aug 2009 12:57
Last Modified:21 Nov 2017 14:16
Publisher:Springer
ISSN:1574-1443
Funders:Department of Science and Technology,New Delhi, India (Grant Nos. SR/S1/IC-03/2005), SPA-DSA University Grants Commission, New Delhi
Publisher DOI:https://doi.org/10.1007/s10904-009-9281-9

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