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Synthesis and structure of nitrones derived from 2-trifluoromethyl bornane 3-imines


Mloston, G; Obijalska, E; Linden, A; Heimgartner, H (2010). Synthesis and structure of nitrones derived from 2-trifluoromethyl bornane 3-imines. Journal of Fluorine Chemistry, 131(5):578-583.

Abstract

The oxidation of exo-2-hydroxy-endo-2-(trifluoromethyl)bornan-3-imines with meta-chloroperbenzoic acid leads – unexpectedly – to the corresponding nitrones in a stereoselective manner. A mixture of the isomeric oxaziridines was obtained upon UV-irradiation of the N-methylnitrone.

Abstract

The oxidation of exo-2-hydroxy-endo-2-(trifluoromethyl)bornan-3-imines with meta-chloroperbenzoic acid leads – unexpectedly – to the corresponding nitrones in a stereoselective manner. A mixture of the isomeric oxaziridines was obtained upon UV-irradiation of the N-methylnitrone.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:May 2010
Deposited On:12 May 2010 14:39
Last Modified:07 Dec 2017 02:12
Publisher:Elsevier
ISSN:0022-1139
Publisher DOI:https://doi.org/10.1016/j.jfluchem.2010.01.001

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