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Unexpected Insertion Reaction of Dimethoxycarbene with Imidazole-2(3H)-thiones


Mloston, G; Heimgartner, H (2010). Unexpected Insertion Reaction of Dimethoxycarbene with Imidazole-2(3H)-thiones. Phosphorus, Sulfur and Silicon and the Related Elements, 185(5-6):1235-1242.

Abstract

The reaction of in situ generated dimethoxycarbene with 1,4,5-trisubstituted imidazole-2(3H)-thiones yields 3-(dimethoxymethyl)imidazole-2(3H)-thiones in good yield via insertion into the N-H bond. The structure of the products was established by spectroscopic data and, in the case of 7b, by X-ray crystallography.

Abstract

The reaction of in situ generated dimethoxycarbene with 1,4,5-trisubstituted imidazole-2(3H)-thiones yields 3-(dimethoxymethyl)imidazole-2(3H)-thiones in good yield via insertion into the N-H bond. The structure of the products was established by spectroscopic data and, in the case of 7b, by X-ray crystallography.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:June 2010
Deposited On:05 Jul 2010 14:44
Last Modified:26 Jan 2017 08:47
Publisher:Taylor & Francis
ISSN:1026-7719
Funders:F. Hoffmann-La Roche AG, Basel, University of Lodz
Publisher DOI:https://doi.org/10.1080/10426501003773761

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