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Dye-modified nanochannel materials for photoelectronic and optical devices


Calzaferri, G; Li, H; Brühwiler, D (2008). Dye-modified nanochannel materials for photoelectronic and optical devices. Chemistry - A European Journal, 14(25):7442-7449.

Abstract

Artificial photonic antenna systems have been realised by incorporating organic dyes into zeolite L. The size and aspect ratio of the cylindrically shaped zeolite crystals can be tuned over a wide range, adding to the versatility of this host material. A 600 nm sized crystal, for example, consists of about 96 000 one-dimensional channels oriented parallel to the cylinder axis. Geometrical constraints imposed by the host structure lead to supramolecular organisation of the guests, allowing high concentrations of non- or only very weakly interacting dye molecules. A special twist is added to these systems by plugging the channel openings with a second type of fluorescent dye, a so-called stopcock molecule. The two types of molecules are precisely tuned to each other; the stopcocks are able to accept excitation energy from the dyes in the channels, but cannot pass it back. The supramolecular organisation of dyes in the zeolite channels corresponds to a first stage of organisation, allowing light-harvesting within the volume of a cylindrical crystal and radiationless energy transport to either the cylinder ends or centre. The second stage of organisation represents the coupling to an external acceptor or donor stopcock fluorophore at the channel entrances, which can then trap or inject electronic excitation energy. The third stage of organisation is realised by interfacing the material to an external device through a stopcock intermediate. We observed that electronic-excitation-energy transfer in dye-zeolite L materials occurs mainly along the channel axis and we have shown that macroscopically organised materials can be prepared. The new materials offer unique possibilities as building blocks for optical, electro-optical and sensing devices.

Abstract

Artificial photonic antenna systems have been realised by incorporating organic dyes into zeolite L. The size and aspect ratio of the cylindrically shaped zeolite crystals can be tuned over a wide range, adding to the versatility of this host material. A 600 nm sized crystal, for example, consists of about 96 000 one-dimensional channels oriented parallel to the cylinder axis. Geometrical constraints imposed by the host structure lead to supramolecular organisation of the guests, allowing high concentrations of non- or only very weakly interacting dye molecules. A special twist is added to these systems by plugging the channel openings with a second type of fluorescent dye, a so-called stopcock molecule. The two types of molecules are precisely tuned to each other; the stopcocks are able to accept excitation energy from the dyes in the channels, but cannot pass it back. The supramolecular organisation of dyes in the zeolite channels corresponds to a first stage of organisation, allowing light-harvesting within the volume of a cylindrical crystal and radiationless energy transport to either the cylinder ends or centre. The second stage of organisation represents the coupling to an external acceptor or donor stopcock fluorophore at the channel entrances, which can then trap or inject electronic excitation energy. The third stage of organisation is realised by interfacing the material to an external device through a stopcock intermediate. We observed that electronic-excitation-energy transfer in dye-zeolite L materials occurs mainly along the channel axis and we have shown that macroscopically organised materials can be prepared. The new materials offer unique possibilities as building blocks for optical, electro-optical and sensing devices.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:14 July 2008
Deposited On:20 Oct 2008 12:26
Last Modified:18 Apr 2018 11:38
Publisher:Wiley-Blackwell
ISSN:0947-6539
Funders:KTI; Grant Number: 7736.2, 9231.2, Chinese ministry of education; Grant Number: 208016, Swiss National Science Foundation; Grant Number: 200020-117591, European Commission; Grant Number: MRTN-CT-2006-035884
OA Status:Closed
Publisher DOI:https://doi.org/10.1002/chem.200800811
Related URLs:http://www.chemeurj.org (Publisher)
Project Information:
  • : Funder
  • : Grant ID
  • : Project TitleKTI; Grant Number: 7736.2, 9231.2
  • : Funder
  • : Grant ID
  • : Project TitleChinese ministry of education; Grant Number: 208016
  • : FunderSNSF
  • : Grant ID
  • : Project TitleSwiss National Science Foundation; Grant Number: 200020-117591
  • : Funder
  • : Grant ID
  • : Project TitleEuropean Commission; Grant Number: MRTN-CT-2006-035884

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