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Azulene based metal-organic frameworks for strong adsorption of H-2


Barman, S; Furukawa, H; Blacque, O; Venkatesan, K; Yaghi, O M; Berke, H (2010). Azulene based metal-organic frameworks for strong adsorption of H-2. Chemical Communications, 46(42):7981-7983.

Abstract

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H-2 interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H-2 molecules in the framework.

Abstract

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H-2 interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H-2 molecules in the framework.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Date:2010
Deposited On:23 Feb 2011 16:39
Last Modified:07 Dec 2017 07:41
Publisher:Royal Society of Chemistry
ISSN:1359-7345
Publisher DOI:https://doi.org/10.1039/c0cc02589e
PubMed ID:20871899
Other Identification Number:ISI:000283260400033

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